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PAHs represent an important class of hazardous organic chemicals that are ubiquitous in the environment and are released from natural or anthropogenic sources. PAHs form, for example, as a result of incomplete combustion of fossil fuels and during the disposal of coal tar and chemical wastes. On the basis of their frequency of occurrence in the environment and their proved mutagenicity and carcinogenicity, 16 PAHs have been selected by the US EPA as priority pollutants. But PAHs with more than 24 carbon atoms cannot be analysed by GC because of their lack of volatility.