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EPR is the only research method that can directly track unpaired electrons, providing in situ and non-destructive information on microscopic scales such as electrons, orbits and nuclei. If the electromagnetic wave with frequency v satisfies the condition of hv=gβH in the direction perpendicular to H, the electrons at the low energy level will absorb the energy of the electromagnetic wave and transit to the high energy level, which is the electron paramagnetic resonance. EPR can only study paramagnetic substances.
Q1. Is lighting required and how to choose the number of test time points?
A. If the sample is a photocatalytic material or a material that changes significantly before and after light, it is necessary to measure the spectra in two different states of darkness and light. The number of lighting test points is the number of points collected at different lighting times. If you want to observe the dynamic changes of the spectral peak shape and peak intensity under the sample illumination conditions, you can collect more spectra at several illumination time points.
Q2. How is the g factor obtained?
A. hv=gβH, h is Planck's constant, g is the spectral splitting factor (referred to as g factor or g value), and β is the natural unit of electronic magnetic moment, called Bohr magneton. As long as H remains constant, the g factor is calculated accordingly.
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