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Investigation of Elastic Properties of Cu–Mo Solid Solution Thin Films by Brillouin Scattering (CAT#: STEM-ST-0120-YJL)

Introduction

The determination of the mechanical properties of thin layers deposited on a substrate is important regarding physical models as well as technical application purposes. Metastable 'solid solutions' of Cu–Mo could be realized by ion beam sputtering or by ion beam mixing of a Cu/Mo multilayered structure, despite the immiscible character of a Cu–Mo system (positive heat of mixing DH). This new class of materials shows interesting structural properties which motivate an increasing number of studies. For example, it was recently reported that this binary system, for a Cu concentration of 30 at. %, presents a very important resistance to the abrasion and allows a good adhesion between Mo and CuInSe2 films which are used as solar cells.




Principle

From a quantum point of view, Brillouin scattering is an interaction of light photons with acoustic or vibrational quanta (phonons), with magnetic spin waves (magnons), or with other low frequency quasiparticles interacting with light. The interaction consists of an inelastic scattering process in which a phonon or magnon is either created (Stokes process) or annihilated (anti-Stokes process). The energy of the scattered light is slightly changed, that is decreased for a Stokes process and increased for an anti-Stokes process. This shift, known as the Brillouin shift, is equal to the energy of the interacting phonon and magnon and thus Brillouin scattering can be used to measure phonon and magnon energies.

Applications

Brillouin scattering is used to determine acoustic velocities and elastic properties of a number of crystalline solids, glasses, and liquids.

Procedure

1. Sample preparation
2. Measurement by scattering detection instrument
3. Data analysis

Materials

Brillouin scattering measurement system (Brillouin spectrometer)
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