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ABA triblock copolymers with H-bonding endsegments have interesting properties. Triblock copolymers have been studied with uridopyrimidinone, urethane, and amide end-groups. If the structure is regular, the H-bonding end-segments can crystallize and as the end-segments are more mobile, they crystallize faster and have a higher crystallinity than mid-segments. If the end-segments were made with a regular structure and mono-disperse in length, the crystallinity was very high, near 100%. These triblock copolymers had a relatively high modulus and relative high elongations at break.