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Study of H2O Ice To Megabar Pressures by Brillouin Scattering (CAT#: STEM-ST-0156-YJL)

Introduction

The phase behavior and compressibility of H2O ice at high pressure and temperature conditions have long been important problems in chemistry, physics, geology, planetology, and biology, and recent research continues to reveal new findings. Because of its open, hydrogen-bonded structure, H2O shows many structural changes between different crystalline forms under pressure. Below 2 GPa and at low temperatures, 12 structural polymorphs and amorphous phases are documented including many metastable forms. Above 2 GPa, three solid phases have been characterized experimentally to date—a high temperature proton disordered paraelectric ice VII, a low temperature proton ordered antiferroelectric ice VIII, and a symmetric hydrogen-bonded ice X.




Principle

From a quantum point of view, Brillouin scattering is an interaction of light photons with acoustic or vibrational quanta (phonons), with magnetic spin waves (magnons), or with other low frequency quasiparticles interacting with light. The interaction consists of an inelastic scattering process in which a phonon or magnon is either created (Stokes process) or annihilated (anti-Stokes process). The energy of the scattered light is slightly changed, that is decreased for a Stokes process and increased for an anti-Stokes process. This shift, known as the Brillouin shift, is equal to the energy of the interacting phonon and magnon and thus Brillouin scattering can be used to measure phonon and magnon energies.

Applications

Brillouin scattering is used to determine acoustic velocities and elastic properties of a number of crystalline solids, glasses, and liquids.

Procedure

1. Sample preparation
2. Measurement by scattering detection instrument
3. Data analysis

Materials

Brillouin scattering measurement system (Brillouin spectrometer)