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Study of Optimization for Aqueous Mixtures by Thermal Diffusion Forced Rayleigh Scattering (CAT#: STEM-ST-0065-YJL)

Introduction

Thermal diffusion describes the migration of molecules in a temperature gradient. The molecular origin of the effect, also called Ludwig-Soret effect, is one of the unsolved problems in physical chemistry. In some cases, even qualitative predictions are impossible. The main practical applications are separation processes such as thermal field flow fractionation of polymers and colloids or isotope separation, characterization of geochemical processes, and combustion. There are many experimental methods such as thermal diffusion cells, thermogravitational columns, thermal lens method, holographic grating methods, field-flow fractionation, and microscopic methods to investigate the thermal diffusion behavior of simple and complex liquid mixtures.




Principle

Forced Rayleigh scattering (FRS) is a light scattering technique used to investigate light-induced grating structures that decay in a relaxational or almost relaxational manner. Such gratings can be created by interference and absorption of two pump beams and probed by a third beam, usually of different frequency. They may consist of spatially varying excited state populations with picosecond lifetimes or of long-lived variations in temperature, composition, and/or density. Forced Rayleigh scattering provides high sensitivity with respect to the amplitude and dynamics of such gratings and allows investigations not accessible by classical scattering techniques.

Applications

Forced Rayleigh Scattering is used to study fluid.

Procedure

1. Sample preparation
2. Measurement by scattering detection instrument
3. Data analysis

Materials

Rayleigh scattering measurement system
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