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ICP–AES is a viable technology for studying fundamental laser ablation processes at atmospheric pressure. Spectral emission intensity in the ICP is proportional to the quantity of mass ablated from sample, assuming the mass does not change the ICP excitation characteristics. Studying the relation between composition and quantity of ablated mass vs. laser properties (such as laser fluence, power density, wavelength, and pulse duration) will aid in understanding laser ablation mechanisms. The ICP is a unique source for chemical analysis applications and studying fundamental mechanisms.