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Aniline is an important chemical raw material, widely used in national defense, printing and dyeing, plastic, paint, pesticide, medicine and other industries. Aniline is a kind of harmful substance that seriously pollutes the environment and harms human health. It can cause cancer, mutagenicity and teratogenesis. Therefore, strict control of aniline content is required in industrial drainage. Supercritical water oxidation technology can be used to determine the total organic carbon in aniline wastewater, so as to judge the pollution degree of wastewater.