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Determination of total organic carbon in karst groundwater by ultraviolet oxidation technology (CAT#: STEM-PPA-0137-LJX)

Introduction

Karst groundwater, also known as karst water, refers to the water in the dissolution cracks and caves of soluble rock formations, and its most obvious feature is that the distribution is very uneven. Karst water-bearing systems are generally rich in water and good in water quality, and are often used as large and medium-sized water sources.
Total organic carbon (TOC) is an important carbon component in the global carbon cycle and the primary food source of the aquatic food chain. Therefore, the measurement of TOC plays an important role in the analysis of carbon flux in aquatic systems and the study of the global carbon cycle. The determination of total organic carbon in karst groundwater is helpful to evaluate the role of organic matter in the global carbon cycle.




Principle

The principle of ultraviolet oxidation method is as follows: Using ultraviolet light to illuminate the water sample to be tested, the water will decompose into hydroxyl and hydrogen groups. The hydroxyl group combines with the oxide to produce CO2 and water, and the total organic carbon content is calculated by measuring the newly generated CO2. When using ultraviolet oxidation method, the oxidation capacity can be improved by adding titanium dioxide, persulfate, etc. The advantage of ultraviolet oxidation method is high oxidation efficiency and simple maintenance, but the disadvantage is that the UV lamp needs to be replaced regularly.

Applications

For the determination of total organic carbon in liquids

Procedure

1. Ultraviolet light illuminates the water sample
2. The water sample is oxidized to produce CO2 and water
3. CO2 content was determined by infrared absorption method
4. Calculate the total organic carbon in the water sample by CO2 content

Materials

• Sample Type:
Karst groundwater

Notes

UV lamps need to be replaced regularly.
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