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Determination of Water Content in Pyrolysis Oil by Distillation (CAT#: STEM-PPA-0123-YJL)

Introduction

Pyrolysis oil is a dark brown organic liquid that mainly consists of a complex mixture of highly oxygenated compounds and water. Its composition depends on the biomass feedstock and the parameters during the pyrolysis process e.g. temperature, heating rate, vapor residence time, etc. Pyrolysis oil has several potential applications. It can be used as a substitute for fuel oil in static applications to generate heat and/or electricity, as an additive in transport fuels or as a source of value-added chemicals. To determine the most appropriate application, a thorough characterization of the pyrolysis oil is absolutely necessary.

A substantial part of pyrolysis oil frequently consists of water. The water content influences the calorific value and the flow properties (viscosity) of the pyrolysis oil, both important parameters when is aimed at fuel applications.




Principle

Azeotropic distillation refers to a series of techniques that destroy the azeotropic composition in distillation to carry out distillation or fractionation, and use two organic solvents to form an azeotrope for distillation.
Azeotropic distillation, also known as azeotropic distillation, is to add a selected third component to the separated mixed liquid to form a new azeotrope with one or more components in the original mixture. And its boiling point is lower than that of any original component. In this way, the new azeotrope is distilled from the top of the column during distillation, while the bottom product is a pure component, thereby achieving the purpose of separating the original mixture.
Azeotropic distillation is suitable for separating mixed liquids with only azeotropic composition and relative volatility close to 1.

Applications

Food industry; Petroleum industry

Procedure

1. Add the sample to the still.
2. Add to collection bottle.
3. Heat.
4. Collect the liquid.
4. Calculate moisture content.

Materials

• Sample Type: liquid or powder
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