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In NaH2PO4-Na2HPO4 solution with pH value of 6.17, accresol green and cationic surfactants such as cetyltrimethylammonium australide (CTMAB) and cetylpyridine australide (CPB) form ionic associations, and the blue color of the solution is diminished. It can be used to determine cationic surfactants in water with a maximum fading wavelength of 614nm.