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Vancomycin is in a class of medications called glycopeptide antibiotics. It works by killling bacteria in the intestines.<br />Glycopyrronium (GLY), a new long-acting muscarinic antagonist was approved in Europe in 2012 for maintenance bronchodilator treatment in adult patients with COPD. This fact raises the need for effective methods to simultaneously determine antibiotics of different classes. In this service, four antibiotics including vancomycin, cefoperazone, sulbactam, and ceftriaxone are determined simultaneously by capillary electrophoresis with capacitively coupled contactless conductivity detection (CE-C4D).