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Radiocarbon Dating of Shells and Carbonates by Carbon-14 Dating Method (CAT#: STEM-EA-0130-ZJF)

Introduction

Terrestrial carbonates, such as shells, corals, and tufas, are excellent candidates for radiocarbon dating. The primary component is calcium carbonate or other forms of carbonate minerals. Sea shells and corals are examples of biogenic carbonates; marls, tufa and other limestones are examples of calcareous deposits.
Radiocarbon dating can be performed on a variety of samples, including shells, corals, bones, and teeth, charcoal, wood, sediments, and groundwater. Each type of material may require a different sample for analysis, so it is important to handle packaging carefully to avoid contamination. By measuring the radiocarbon content of organic material, only organic material can be dated. A living organism exchanges carbon with its environment until it dies, at which point the carbon exchange ceases and the C-14 (a radioactive isotope) begins to decay. In the laboratory, the amount of C-14 in the sample can be used to estimate the age of organic material, organisms, plants, or animals. Before analysis, additional steps may be required, such as decontamination or converting the sample into a form that is more suitable for measurement.




Principle

In order to determine the age of an object, radiocarbon dating relies on the unique properties of Carbon-14, a radioactive isotope of carbon found in organic materials. Nature produces the Carbon-14 isotope as a result of cosmic rays bombarding the lower stratosphere and upper troposphere, producing neutrons as they break through the atmosphere, converting nitrogen-14 atoms into C-14. Radiocarbon combines with oxygen in the atmosphere to form carbon monoxide (CO), which is then dissolved in the oceans, distributed into the biosphere, and absorbed by plants via photosynthesis, which are subsequently consumed by living organisms. As long as a plant or animal is alive and in equilibrium with its environment, it exchanges carbon with it until the moment of its death, when the exchange ceases and the C-14 continues to decompose. A radiocarbon date can be determined from samples of organic remains using the radiocarbon found in the samples. The radioactive decay property of C-14 makes it less detectable the older the sample is, which serves as a marker for determining the age of the organic sample. In order to avoid incorrect results, however, other preparations, conversions, and considerations must be taken into account.

Applications

Shells & Carbonates, Groundwater, Bones & Teeth, Charcoals / Woods, Sediments, etc.

Procedure

1. Sample preparation
2. Series of chemical reactions to convert all carbon atoms present into benzene
3. Addition of scintillator to benzene sample
4. Liquid scintillator spectrometer counts the number of decays occurring per minute
5. Computer analysis of data and date of sample determined

Materials

• C-14 Dating Device / Accelerator Mass Spectrometer
• Sample material
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