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Cobalt oxide compounds are now widely used for various materials such as catalyst, semiconductors, and so on. For example, recent studies have shown that cobalt oxide catalysts are highly active for oxidation reaction of CO at ambient temperature. In order to study reaction mechanisms including the cobalt oxide catalyst, it is important to know the microscopic physical and chemical properties of this compound. Ion mobility spectrometry (IMS) is known as a method for characterizing geometrical structures of gas-phase ions from the measurement of a drift velocity, vd, of ions in an electric field.