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Bismuth silicone oxide (Bi12SiO20, BSO) crystals are highly efficient photoconductors with a low dark conductivity, that allows a build-up of large photo-induced space-charges. Tremendous photoconductivity and electro-optic properties make BSO crystals attractive in a range of applications: spatial light modulators, optical switches, phase conjugation mixers. BSO crystals are grown by modified Czochralski method and available in up to 3‘‘ diameter aperture size.