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Study of Thermal stability of material by Thermal Gravimetric Analysis (TGA) (CAT#: STEM-ACT-0032-WXH)

Introduction

TGA can be used to evaluate the thermal stability of a material. In a desired temperature range, if a species is thermally stable, there will be no observed mass change. Negligible mass loss corresponds to little or no slope in the TGA trace. TGA also gives the upper use temperature of a material. Beyond this temperature the material will begin to degrade.
TGA is used in the analysis of polymers. Polymers usually melt before they decompose, thus TGA is mainly used to investigate the thermal stability of polymers. Most polymers melt or degrade before 200 °C. However, there is a class of thermally stable polymers that are able to withstand temperatures of at least 300 °C in air and 500 °C in inert gases without structural changes or strength loss, which can be analyzed by TGA.




Principle

Thermogravimetric analysis or thermal gravimetric analysis (TGA) is a method of thermal analysis in which the mass of a sample is measured over time as the temperature changes. This measurement provides information about physical phenomena, such as phase transitions, absorption, adsorption and desorption; as well as chemical phenomena including chemisorptions, thermal decomposition, and solid-gas reactions (e.g., oxidation or reduction).

Applications

• Thermal characterization of polymers.
• Determination of the composition of alloys and mixtures.
• Determining the purity and thermal stability of both primary and secondary standards.

Procedure

TGA analysis is performed by gradually raising the temperature of a sample in a furnace as weight is measured on an analytical balance that remains outside the furnace. Thermogravimetric analysis instrument measures the changes in a sample's weight in a particular temperature by enclosing the sample in an oven.

Materials

Thermogravimetric analyzer
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