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Study of Thermodiffusion in Magnetic Colloids by Forced Rayleigh Scattering (CAT#: STEM-ST-0067-YJL)

Introduction

Magnetic colloids, also called ferrofluids, are divided in two classes, ionic or surfacted, according to the nature of the interparticle repulsion: electrostatic if the particles are coated with ionic ligands, steric if the particles are coated with surfactants. Ferrofluids exhibit very interesting properties under an applied magnetic field and have many technical uses. If a magnetic colloid sample is placed in the interference region of two coherent intersecting laser beams (called here pump beams) having the same polarization directions, the nanoparticle concentration and, therefore, the index of refraction become spatially modulated with the same periodicity as that of the interference pattern.




Principle

Forced Rayleigh scattering (FRS) is a light scattering technique used to investigate light-induced grating structures that decay in a relaxational or almost relaxational manner. Such gratings can be created by interference and absorption of two pump beams and probed by a third beam, usually of different frequency. They may consist of spatially varying excited state populations with picosecond lifetimes or of long-lived variations in temperature, composition, and/or density. Forced Rayleigh scattering provides high sensitivity with respect to the amplitude and dynamics of such gratings and allows investigations not accessible by classical scattering techniques.

Applications

Forced Rayleigh Scattering is used to study fluid.

Procedure

1. Sample preparation
2. Measurement by scattering detection instrument
3. Data analysis

Materials

Rayleigh scattering measurement system
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