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Quantitative determination of nitrogen in iron by spark source mass spectrometry (CAT#: STEM-ST-0275-LJX)

Introduction

Nitrogen impurities present in iron are estimated by thespark source mass spectroscopic method; the inherent diff-culty of this analysis lies in the close proximity of the 14N+and 5Fe4+ lines. Four samples were analyzed by this methodwith the nitrogen content (28 to 284 wt. ppm) previously de-termined by a classical method of analysis.




Principle

By using vacuum spark discharge, the energy accumulated in a small volume can make the material in the volume suddenly evaporate and ionize, so as to obtain the characteristic ion current information.

Applications

(1) Solid spark source mass spectrometry: impurity analysis of high-purity materials, which can be applied to semiconductor materials, non-ferrous metals, and building materials industries;
(2) Gas isotope mass spectrometry: determination of stable isotopes C, H, N, O, S and radioactive isotopes Rb, Sr, U, Pb, K, Ar, which can be applied to geology, petroleum, medicine, environmental protection and agriculture.

Procedure

(1) An electric field is applied between the electrodes to ionize part of the carrier gas (such as argon) in the electric field;
(2) The "cathode ray" or "anode ray" generated by ionization accelerates in the direction of the opposite polarity in the residual gas, bombards the anode or cathode, and vaporizes a part of the substance to be measured on the plate;
(3) Part of the atoms of the vaporized substance are ionized in the subsequent discharge process.

Materials

• Sample Type:
Nitrogen

Notes

Before starting the machine, check whether the water (water cooler), electricity, gas (argon/nitrogen), temperature, humidity, and exhaust air of the instrument are normal.
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