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Study of the Elastic Constants and Related Properties of β-HMX by Brillouin Scattering (CAT#: STEM-ST-0110-YJL)

Introduction

The structure-function relationship for many materials remains a fundamental question in solid-state research. Concomitant with a broader understanding of this relationship, the properties of solid-state materials are becoming increasingly tunable. This comprehension, particularly for the mechanical properties, is essential to the development of secondary explosives, such as HMX scyclotetramethylenetetranitramined, that characteristically balance low sensitivity to detonation with high power. Elasticity is fundamental to understanding such materials' mechanical response to stress. The elastic constants, which arise from intermolecular forces, provide a window into the microscopic interactions that affect phonon propagation, lattice compressibility, and thermal conductivity.




Principle

From a quantum point of view, Brillouin scattering is an interaction of light photons with acoustic or vibrational quanta (phonons), with magnetic spin waves (magnons), or with other low frequency quasiparticles interacting with light. The interaction consists of an inelastic scattering process in which a phonon or magnon is either created (Stokes process) or annihilated (anti-Stokes process). The energy of the scattered light is slightly changed, that is decreased for a Stokes process and increased for an anti-Stokes process. This shift, known as the Brillouin shift, is equal to the energy of the interacting phonon and magnon and thus Brillouin scattering can be used to measure phonon and magnon energies.

Applications

Brillouin scattering is used to determine acoustic velocities and elastic properties of a number of crystalline solids, glasses, and liquids.

Procedure

1. Sample preparation
2. Measurement by scattering detection instrument
3. Data analysis

Materials

Brillouin scattering measurement system (Brillouin spectrometer)
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