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Femtosecond transient absorption spectroscopy (fs-TAS) technology is an important method for ultrafast dynamics research, which combines femtosecond time-resolved pump-probe technology with absorption spectroscopy. It has been widely used in the research of biology, physics, chemistry, materials and so on. In the transient absorption experiment, a beam of pump light is used to excite the molecules to be tested to the excited state, and another beam of probe light is used to detect the spectral properties of the sample molecules in the excited state at a certain delay time ∆t. Recording the absorption spectra under all different ∆t can obtain the complete excited state absorption spectrum of the sample molecule to be measured with time, and obtain the kinetic information of the excited state after further processing and analysis. The femtosecond transient absorption spectrometer is an analytical instrument used in the field of materials science.
Q1. What is a transient absorption spectrometer?
A. It is an instrument used to measure the properties of transient substances produced after laser excitation.
Q2. What is the role of femtosecond transient absorption spectroscopy?
A. The femtosecond transient is the most common form of time-resolved spectroscopy. Through the analysis of femtosecond transient absorption spectra, we can obtain rich photophysical information such as ground state bleaching, stimulated emission and excited state absorption. It can reflect the subsequent photophysical and photochemical relaxation process of the sample in the excited state, and can also reflect the change of the number of particles in the same energy state with the delay time.
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