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Measurement of Viscosity of Electrospun Chitosan/Poly(Vinyl Alcohol) Membranes by Rotating Viscometer Method (CAT#: STEM-PPA-0035-YJL)

Introduction

Recently, electrospinning, or called electrostatic spinning, has emerged as an efficient technique for preparation of ultrafine fibers with diameters ranging from several nanometers to several microns. It has been widely accepted as the simplest and least expensive method to fabricate nanofibers or nanofibrous membranes from a variety of synthetic or natural polymers. The electrospun non-woven membranes exhibit high surface area and porosity. Thus, they may have potential applications such as tissue engineering scaffolds, wound dressings, composite reinforcements, protective clothings, and filters.
Chitosan, a copolymer of glucosamine and N-acetyglucosamine units linked by 1–4 glucosidic bonds, is a cationic polysaccharide obtained by alkaline deacetylation of chitin. PVA is a water-soluble polymer with semi-crystalline molecular structure. It shows good properties, such as nontoxicity and chemical stability. The electrospinning phenomenon itself involves basic and significant issues in polymer solutions, in which viscosity, surface tension, and conductivity are the critical factors for the successful preparation of nanofibers by electrospinning.




Principle

The principle of the rotating viscometer method to measure the force acting on a rotor (torque) when it rotates at a constant angular velocity (rotational speed) in a liquid. Rotating viscometers are used for measuring the viscosity of Newtonian (shear-independent viscosity) or non-Newtonian liquids (shear dependent viscosity or apparent viscosity). Rotating viscometers can be divided in 2 groups, namely absolute and relative viscometers. In absolute viscometers the flow in the measuring geometry is well defined.
The measurements result in absolute viscosity values, which can be compared with any other absolute values. In relative viscometers the flow in the measuring geometry is not defined. The measurements result in relative viscosity values, which cannot be compared with absolute values or other relative values if not determined by the same relative viscometer method. Different measuring systems are available for given viscosity ranges as well as several rotational speeds.

Applications

Mineral oil industry; Food industry; Cosmetic/pharmaceutical industry; Petroleum industry; Chemical industry

Procedure

1. Pour the liquid into the measuring cup.
2. Insert the spindle into the liquid.
3. Rotate the spindle and measure the resistance.

Materials

• Sample Type: liquid, gel-like, or semi-solid everyday substances
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