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In Situ Characterization of Nanoparticles Using Rayleigh Scattering (CAT#: STEM-ST-0008-YJL)

Introduction

Since their discovery in 19911 carbon nanotubes have attracted great attention due to the expectation that they could lead to electronic devices with unprecedented capabilities. So far this expectation has not been fulfilled, mainly because it has not been possible to access large yields of single-walled nanotubes (SWNT) with a well-defined chirality, which is the key factor governing their electronic properties. Defect-free SWNTs are typically extracted from synthesis products that contain a mixture of defective and non defective nanotubes.
A major stumbling block on the way of devising controlled synthesis processes is the lack of detailed microscopic knowledge of the processes responsible for the growth of the carbon nanoparticles. To better understand these processes experimental techniques that can characterize the particles in situ during the early stages of growth would be extremely useful.




Principle

Resonance Rayleigh scattering (RRS) is similar to Rayleigh scattering in nature. Resonance Rayleigh scattering is a special elastic scattering produced when the wavelength of Rayleigh scattering (RS) is located at or close to its molecular absorption band. The key to generating RRS is: when the scattering is at or close to the absorption band of the scattering molecule, since the electron absorbs the electromagnetic wave at the same frequency as the scattering frequency, the electron strongly absorbs the photon energy due to resonance and re-scatters. Its scattering intensity is several orders of magnitude higher than that of pure Rayleigh scattering, and it no longer obeys the Rayleigh law of I∝λ-4. This absorption-rescattering process is called resonance Rayleigh scattering (RRS).

Applications

Resonance Rayleigh scattering is used to the study of aggregation of chromophores on biological macromolecules and the determination of biological macromolecules such as nucleic acid, proteins and heparin, further, it has been used in the determination of trace amounts of inorganic ions and the cationic surfactant by means of ion association reactions with some dyes. In addition, it has been applied to the study of nanoparticles in liquid and the determination of β-cyclodextrin inclusion constant and the critical micelle concentration of surfactant.

Procedure

1. Sample preparation
2. Measurement by scattering detection instrument
3. Data analysis

Materials

Rayleigh scattering measurement system
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